A model to explain graphene bending behaviour

Graphene ‒ a single layer of carbon atoms arranged in a lattice ‒ is the strongest material in the world and so thin that it is flexible, the researchers said. It is considered one of the key ingredients of future technologies. Most of the current research on graphene targets the development of nanoscale electronic devices. Yet, researchers say that many technologies require an understanding of the mechanics of graphene, particularly how it flexes and bends, to unlock their potential.

A solution to the fundamental graphene property 

A group of engineers at the University of Illinois tried to determine how much energy it takes to bend multilayer graphene combining atomic-scale experimentation with computer modelling.

The bending stiffness of a material is one of its most fundamental mechanical properties,” said Edmund Han, materials science and engineering graduate student. “Even though we have been studying graphene for two decades, we have yet to resolve this very fundamental property. The reason is that different research groups have come up with different answers that span across orders of magnitude.”

The team discovered why previous research efforts disagreed. “They were either bending the material a little or bending it a lot,” said Jaehyung Yu, mechanical science and engineering graduate student. “But we found that graphene behaves differently in these two situations. When you bend multilayer graphene a little, it acts more like a stiff plate or a piece of wood. When you bend it a lot, it acts like a stack of papers where the atomic layers can slide past each other.”

This work shows that even though everyone disagreed, they were actually all correct,” said Arend van der Zande, professor of mechanical science and engineering. “Every group was measuring something different. What we have discovered is a model to explain all the disagreement by showing how they all relate together through different degrees of bending.”

The research steps

To make the bent graphene, Yu fabricated individual atomic layers of hexagonal boron nitride, another 2-D material, into atomic-scale steps, then stamped the graphene over the top. Using a focused ion beam, Han cut a slice of material and imaged the atomic structure with an electron microscope to see where each graphene layer sat. The team then developed a set of equations and simulations to calculate the bending stiffness using the shape of the graphene bend. By draping multiple layers of graphene over a step just one to five atoms high, the researchers created a controlled and precise way of measuring how the material would bend over the step-in different configurations.

In this simple structure, there are two kinds of forces involved in bending the graphene,” said Pinshane Huang, a materials science and engineering professor and study co-author. “Adhesion, or the attraction of atoms to the surface, tries to pull the material down. The stiffer the material, the more it will try to pop back up, resisting the pull of adhesion. The shape that the graphene takes over the atomic steps encodes all the information about the material’s stiffness.”

The study systematically controlled exactly how much the material bent and how the properties of the graphene changed.

Because we studied graphene bent by different amounts, we were able to see the transition from one regime to another, from rigid to flexible and from plate to sheet behaviour,” said mechanical science and engineering professor Elif Ertekin, who led the computer modelling portion of the research. “We built atomic-scale models to show that the reason this could happen is that the individual layers can slip over each other. Once we had this idea, we were able use the electron microscope to confirm the slip between the individual layers.”

Possible applications

The new results could have implications for creating machines small and flexible enough to interact with cells or biological material.

Cells can change shape and respond to their environment, and if we want to move in the direction of microrobots or systems that have the capabilities of biological systems, we need to have electronic systems that can change their shapes and be very soft as well,” van der Zande said. “By taking advantage of interlayer slip, we have shown that the graphene can be orders of magnitude softer than conventional materials of the same thickness.”

Source: University of Illinois. The findings of the research are reported in the journal Nature Materials.

Graduate student Edmund Han, left, professor Elif Ertekin, graduate student Jaehyung Yu, professor Pinshane Y. Huang, front, and professor Arend M. van der Zande have determined how much energy it takes to bend multilayer graphene – a question that has long eluded scientists. Credit: Stephanie Adams

Leggi anche

Il Centro tomografico di TEC Eurolab si dota di un acceleratore lineare dieci volte più potente rispetto ai due già posseduti. Permette di effettuare analisi di componenti di grande spessore e di materiali e leghe ad altissima densità, inclusi i materiali per l’additive manufacturing e dei materiali compositi. Questa tecnica di indagine non distruttiva avanzata consente all’azienda di offrire un range di applicazioni unico nel panorama europeo e risponde alle esigenze del settore aeronautico e automotive…

Leggi tutto…

Composite UK, l’associazione di riferimento per l’industria britannica dei materiali compositi, ha diffuso una guida per le buone pratiche in materia di resistenza al fuoco dei compositi in polimeri fibroriforzati (Fire Performance of Composites Good Practice Guide). Data la complessità del comportamento dei materiali compositi in relazione al fuoco, la guida punta a rispondere all’esigenza del mercato e del mondo della ricerca di approfondire la conoscenza di questo parametro….

Leggi tutto…

Grazie alla collaborazione tra AVK, l’Istituto per i materiali compositi (IVW) di Kaiserslautern (Germania) e CAMPUS oggi è possibile avere a disposizione dati standardizzati per i materiali termoplastici rinforzati con fibre continue (cFRTP). Notevole il vantaggio per le industrie produttrici e per i settori che impiegano componenti a base di cFRTP. Fino a oggi questi materiali erano rimasti esclusi dai database CAMPUS a causa della mancanza di caratterizzazioni industriali comuni…

Leggi tutto…

Il futuro e lo sviluppo produttivo dei settori Aerospaziale, Aeronautico, Motorsport, Automotive&Luxury cars, Eolico e Nautico è orientato verso la ricerca e l’innovazione dei materiali compositi in particolare quelli a matrice polimerica o FRP, Fiber Reinforced Polymer e le fibre di carbonio. Professionisti, ingegneri e tecnici, che ne conoscono caratteristiche e potenzialità e sanno sfruttarne e guidarne al meglio la performance, sono oggi alcune delle figure più ricercate da tutte le principali realtà industriali e produttive….

Leggi tutto…